In the picture, from left to right: (top) Pierre Louette, Director of the Physics Department; François Briard, Head of the Science Portal Group (CERN); Julien Colaux, IBA specialist, physics researcher; Boris Hespeels, biology researcher; Alexandre Mayer, physics researcher; Anne-Catherine Heuskin, physics and biophysics researcher. (bottom) André Füzfa, astrophysicist and mathematics researcher; Serge Mathot, Applied Physicist (CERN) and Michaël Lobet, physics researcher.

The love affair between CERN and UNamur goes back a long way. CERN's accelerator complex and experimental program are very different and much larger than those of UNamur's Physics Department, but the fields in which the two institutions work have much in common.

In addition, both guests have a personal history with UNamur. The Physics Department was pleased to welcome Serge Mathot, Referent Applied Physicist (CERN) and alumni of the UNamur Physics Department (1992), as well as François Briard, Group Leader Science Portal (CERN), and alumni of the UNamur Faculty of Computer Science (1994).

The activities began with a meeting between the guests, Rector Annick Castiaux, Vice-Rector for Research Carine Michiels, Physics Department Director Pierre Louette and several other members of the Physics and Biology Department. After a general presentation of the University, the participants pointed out the missions shared by both institutions: research and the transfer of technology and knowledge, service to society, scientific popularization and education and training.

.

Physics lunch - CERN presentation

The physics lunch is the monthly meeting between students and members of the physics department and a professional, alumni or not, coming to explain his or her background and what he or she does on a daily basis as a physicist.

During this meeting, attended by around 80 people, François Briard and Serge Mathot presented CERN, the world's largest laboratory for particle physics. CERN's mission is to understand the most elementary particles and the laws of our universe.

At the end of the seminar, the students came away with stars in their eyes. Indeed, opportunities for internships or even first jobs at CERN are possible for physicists but also in many other fields.

Some internship programs at CERN are particularly well suited to the needs of young Belgian students.

The vast majority of physicists working with CERN (over 13,000) are in fact sent to CERN for varying periods of time by their employing national research institutes. CERN offers an exceptional opportunity to develop international experience under excellent conditions, in an environment that is unique in the world! What an inspiration for our young students!

The projet d'Action Recherche Concertée (ARC) PHOENIX aims to renew our understanding of medieval parchments and ancient coins. Artificial intelligence will be exploited to analyze the data generated by material characterization.

This joint study between the Department of Physics and the Namur Institute of Structured Matter (NISM) and the Department of History and the Institut Patrimoines, Transmissions, Héritages (PaTHs) will address questions relating to the production chain and use of these objects and materials in past societies.

At the same time, Serge Mathot presented a seminar in heritage science attended by some 50 people. In particular, he presented his research and the brand-new ELISA accelerator: a miniaturized gas pedal capable of delivering a 2 MeV proton beam used to perform real measurements at the Science Portal.

Having the opportunity to exchange views with François Briard, Group Leader of the CERN Science Portal is a rare opportunity. Comparing outreach activities has opened up new avenues, discovering and sharing approaches, assessing what works and what doesn't, depending on the target audience. A highly satisfying enrichment for the members present from Confluent des Savoirs (CDS), the University of Namur's research outreach and dissemination service.

Professor Anne-Catherine Heuskin and Dr. Boris Hespeels are currently working on the BEBLOB project, a Belspo project with ESA support, as part of the UNIVERSEH (European Space University for Earth and Humanity) alliance. They are particularly interested in its astonishing ability to withstand high doses of radiation.

Anne-Catherine Heuskin also works in radiobiology. Particles are used to irradiate cancerous cells in order to destroy their genetic material and prevent them from proliferating: this is the basis of radiotherapy and proton therapy.

The meeting confirmed the willingness of FaSEF and UNamur to get involved in coordinating the Belgian National Teacher Programme in French-speaking Belgium, which CERN intends to relaunch in 2026. Consideration was also given to other avenues for teacher training, such as CERN's forthcoming involvement in the "Salle des Pros", the training venue for the various players involved in teacher training at UNamur.

The TRAKK is Namur's creative hub supported by 3 complementary partners in the field: BEP, KIKK, and UNamur. In addition to the venue, François Briard was able to visit the ProtoLab , which bridges the gap between ideas and industry by being a decentralized research and development hub accessible to SMEs and project leaders by offering advanced support in prototyping products or services.

Graduating in law and information technology management (DGTIC) in 1994 after his bachelor's and master's degrees in computer science in 1993, François Briard works at CERN, the European Organization for Nuclear Research in Geneva, the world's largest particle physics laboratory.

During his school career, which was 100% at UNamur, he was vice-president of the Régionale namuroise and student delegate during his years as a candidate in economic and social sciences, computer science option.

Thanks to the multidisciplinary training provided at UNamur, he was able to seize several opportunities to redirect his career at CERN, where he was an information systems engineer from 1994 and then, from 2014, redirected his career until he became Group Leader of the Science Portal, which is CERN's general public communications center.

Serge Mathot obtained his doctorate in applied sciences from UNamur in 1992, following his bachelor's degree in physical sciences in 1985.

He then carried out a post-doctorate at the Joint Research Center (EU science hub) in Geel, which aims to bring together multidisciplinary skills to develop new measurement methods and tools such as reference materials.

He perfected his expertise in physical metallurgy before joining CERN in 1995 as a Referent Applied Physicist. He has worked on numerous research projects (CLOUD, MACHINA, ELISA...) and developed numerous parts for the manufacture of CERN's gas pedals.

CERN, the European Organization for Nuclear Research, is one of the world's largest and most prestigious scientific laboratories. Its vocation is fundamental physics, the discovery of the constituents and laws of the Universe. It uses highly complex scientific instruments to probe the ultimate constituents of matter: the fundamental particles. By studying what happens when these particles collide, physicists understand the laws of Nature.

The instruments used at CERN are particle gas pedals and detectors. Gas pedals carry beams of particles at high energies to collide with other beams or fixed targets. Detectors observe and record the results of these collisions.

Founded in 1954, CERN is located on either side of the French-Swiss border, near Geneva. It was one of the first organizations on a European scale and today has 25 member states, including Belgium.

This wonderful initiative is the result of a reflection on the integration of quantum chemistry courses at the University of Sfax initiated by Professors Mahmoud TRABELSI (University of Sfax and alumnus of the University of Namur), Besma HAMDI (University of Sfax) and Benoît CHAMPAGNE (University of Namur). The reflection has been matured over the last two decades, during which time several students from Pr. TRABELSI's team have stayed at Pr. CHAMPAGNE's laboratory.

The aim: to add a computational quantum chemistry component to their research into synthetic chemistry, including syntheses from biobased substances.

A PhD student in chemistry at the University of Sfax, Dhouha ABEIRA, is also involved in the project. She is doing an ERASMUS+ internship in Pr. CHAMPAGNE's laboratory to study the optical properties of molecular crystals.

Students were introduced to the calculation of reaction energies and the simulation of UV/visible absorption spectra. These two applications are typical of activities in quantum chemistry, as they are directly linked to the understanding of reaction phenomena and the development of new compounds for molecular optics.

Emphasis has also been placed on certain technical aspects of the calculations in order to train students in the development of computational protocols according to the questions addressed.

The courses were delivered by an inter-university team.

For the Department of Chemistry at the University of Namur:

• Professor Benoît CHAMPAGNE, Director of the Laboratoire de Chimie Théorique (LCT) of the Unité de Chimie Physique Théorique et Structurale (UCPTS);
• Dr. Vincent LIÉGEOIS, for remote IT support and whose suite of programs DrawSuite, a series of applications designed to provide tools for analyzing molecular structures and properties, was much appreciated;
• Frédéric WAUTELET of the Plateforme Technologique de Calcul Intensif (PTCI) for remote computing support and who has prepared a cluster (pleiades) dedicated to training.

For the University of Sfax Chemistry Department:

• The Dr. Mohamed CHELLEGUI, from the organic chemistry laboratory, for preparing practical work;
• Dhouha ABEIRA, PhD student in chemistry, for preparing practical work and assisting students from Sfax.

The teaching teams warmly thank the International Relations teams at the University of Namur and the University of Sfax for their help in setting up and monitoring the ERASMUS+ project.

• This research, still at the experimental stage, is based on a new formulation of electrochromic material: MoWOx, a mixed molybdenum-tungsten oxide
• This advance makes it possible to envisage "dual-band" functionality, i.e. selective and independent modulation of incoming light and heat flows
• The results have been published in the journals Advanced Optical Materials and ACS Applied Optical Materials

Scientists from the University of Liège (ULiège) and the University of Namur (UNamur) have developed an innovative electrochromic material capable of independently regulating light and heat in buildings. This breakthrough, based on a mixed molybdenum-tungsten oxide (MoWOx), paves the way for even more efficient and energy-saving smart windows.

Electrochromic windows are smart glazings capable of modulating their coloration, or more generally their state of transparency or opacity, when an external electric current is applied to it. This property makes it possible to control the intensity of solar radiation entering a building, without the need for blinds or curtains. This type of window is already manufactured industrially and used technologically in some buildings, but current products do not allow separate control of visible light (VIS) and near-infrared radiation (NIR), respectively linked to incident brightness and heat.

Researchers at ULiège and UNamur, thanks to support from the Fonds de la Recherche Scientifique (FNRS), have thus developed a new formulation of electrochromic material, entitled MoWOx, based on a "dual-band" functionality enabling selective and independent modulation of incoming light and heat fluxes.

Through this new formulation, the scientific teams have demonstrated the occurrence of an innovative optical mode, known as "warm", for the first time for this type of oxide. In this mode, the glass remains transparent to infrared radiation, allowing heat to pass through, while only partially filtering out visible light. This feature is particularly interesting for cold climates and winter periods, where maximizing solar heat gain while reducing solar glare can significantly reduce building energy consumption, particularly in terms of heating and artificial lighting.

This "dual-band" functionality is based on the incorporation of nanostructured plasmonic compounds into the smart glass. A plasmonic material is one whose free electrons can oscillate collectively under the effect of light. It can then selectively absorb, reflect or scatter light, depending on its composition and structure. And it is precisely in the application of these plasmonic properties of MoWOx to the case of smart glazing that this innovation lies.

On this basis, the composition and morphology of plasmonic nanostructures directly influence the optical selectivity of filtering, enabling glazing to be tailored more precisely to users' needs.

Future intelligent glazing incorporating these new components could ultimately revolutionize energy management in buildings. In a context where the energy transition remains a top priority, these innovative windows will help to achieve carbon neutrality targets and build near-zero energy buildings.

Florian Gillissen, researcher at the University of Liège and first author of the paper published in Advanced Optical Materials:"Thanks to this technology, we can adjust the transmission of light and heat through windows in real time, which represents a giant step forward for the energy optimization of buildings."

Professor Michaël Lobet, FNRS Qualified Researcher and first author of the paper published in ACS Applied Optical Materials: "Theoretical and numerical modeling was carried out at UNamur in Professor Luc Henrard's team, while material synthesis and characterization was carried out under the direction of Professor Rudi Cloots and Dr. Anthony Maho from the University of Liège. It is these synergies between theoretical modeling and fabrication that have enabled the characterization of these MoWOx materials."

The aim of this FNRS-funded research project (PDR) is to deepen knowledge of the complex crystalline phases of simple salts. The project aims to strengthen international research activities, which began in 2016 and led to the publication of the first results in Nature in 2021. Read the article online...

FK phases have been known since 1959 as a large family of metal alloys, but the study demonstrated that simple pharmaceutical molecules can crystallize with similar complexity, something not previously known.

With this new project, the researchers aim to go one step further, using mainly solid-state nuclear magnetic resonance (NMR) and X-ray diffraction (XRD) techniques on powders and single crystals. This study will be carried out in collaboration with other researchers at the NISM Institute (Nikolay Tumanov, Carmela Aprile and Johan Wouters), as well as collaborators working in other countries, such as Riccardo Montis (University of Urbino, Italy) and Simon Coles (Director of the National Crystallography Service (NCS), University of Southampton, UK).

The research project (PDR) "NPN cofactor synthesis and roles" is at the interface between fundamental biochemistry and enzymology. It is based on the recent discovery, by a team at UCLouvain, of a new cofactor, named NPN, with a highly original structure. It is a dinucleotide bearing a nickel complex. It is involved in important enzymatic reactions, but little is known about its reactivity, biosynthesis and mechanism of action. Moreover, it is present in 20% of bacterial genomes and 50% of Archaea (archaeobacteria) genomes, but only a tiny fraction of the enzymes employing it have been characterized.

The research project is based on the complementary expertise of Benoit Desguin (UCLouvain, biochemistry) and Stéphane Vincent (bio-organic chemistry). The main aim of the project is to understand the role and mechanism of this cofactor through biochemical, structural and kinetic studies. Analogues of the NPN cofactor will be synthesized by the UNamur team: they will be designed to elucidate the mode of interaction and reaction of the NPN cofactor with the enzymes employing it.

This research project (PDR) is a co-promotion of Professors Tom Leyssens (UCLouvain) and Johan Wouters (UNamur). It aims to bring the process of uprooting by crystallization into the era of "green chemistry".

Uprooting is a term used in chemistry to describe the process of separating a racemic mixture into its two enantiomers, i.e. the chiral (left and right) forms of a molecule. In the pharmaceutical industry, 50% of marketed drug compounds contain a chiral center, which is essential to their functioning. When one enantiomer has the desired pharmacological effect, the other may be inactive or have undesirable effects. For this reason, new drugs are often marketed as enantiopure compounds (i.e. free of their impure "chiral twin").

The most common way of obtaining chiral drugs still involves the formation of a racemic mixture. This can then be produced by chemical or physical separation techniques, with a yield loss of 50%. If the compound in question is "racemizable", the unwanted enantiomer can technically be converted back into a racemic mixture, resulting in a theoretical yield of 100%. Over the past decade, various crystallization-based uprooting methodologies have been developed. However, all these methods require the use of large quantities of solvent, as they are crystallization processes.

This research aims to take these processes to the next level, not only by making them more efficient (less time-consuming), but also by bringing them into the realm of "green chemistry". To this end, the researchers are proposing mechanochemical variants for conglomerates and racemic compounds.

These processes will be

• Inherently "green", since the unwanted enantiomer is transformed into the desired enantiomer;
• Enabled by mechanochemistry, which eliminates the need for solvent, making them "greener" than solution-based methods.
• The "greenest" possible, thanks to their efficiency (very fast timescale and low energy consumption).

This funding will enable the acquisition of high-throughput isothermal titration calorimetry (ITC) equipment, unique in the Wallonia-Brussels Federation. This is a high-resolution, non-destructive method enabling complete characterization of the chemical details of an interaction in solution.

His acquisition will enable UNamur chemists, but also their collaborators, to analyze any bond, in a vast field of application, extending from biochemistry to supramolecular chemistry.

"ONL molecular switches "in all their states": from solutions to functionalized surfaces and solids."

This PhD thesis within the Theoretical Chemistry Laboratory (Department of Chemistry) and the Multiscale Modeling through High-Performance Computing (HPC-MM) Cluster of the NISM Institute aims to develop innovative multiscale computational methodologies to study and optimize multistate and multifunctional molecular switches, key components of logic devices and new generations of data storage technologies.

In addition to variations in linear optical responses, it is advantageous to consider changes in nonlinear optical responses (NLOs), which enable high-resolution data readout while avoiding their destruction. The main objective is to predict and interpret the ONL responses of these molecular switches in different matter environments, namely in solution, grafted onto surfaces and in the solid state.

In addition, particular attention will be paid to modeling defects and orientational disorder within materials to better represent real-world conditions. These predictive methods will be validated experimentally through close collaborations with synthesis and characterization teams.

Research at NISM revolves around a variety of research topics in organic chemistry, physical chemistry, (nano)-materials chemistry, surface science, optics and photonics, solid-state physics, both from a theoretical and experimental point of view.

Researchers' expertise is recognized in the synthesis and functionalization of molecular systems and innovative materials, from 0 to 3 dimensions.